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Corn gluten meal, not cornmeal. It only works on seeds so you have to spread before you see any undesirables. Hard to believe it works but sure has great press.

Heat will kill annual weeds. I use a heat gun for weeds growing in paving but a torch would be so satisfying! Many weeds smell quite tasty cooked too. I've had better success with that than full strength vinegar.

I'd be wary of granular weed and feed as it has to stick to the leaf to work and is probably still granular at that point. Could get stuck in fur and have to be licked off by the dog.

I'm sure the sprays are safe but I pull by hand or use a scuffle hoe.
 
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